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-   -   Nissan Ester Oil (http://www.the370z.com/nissan-370z-general-discussions/3530-nissan-ester-oil.html)

370Z Purist 07-11-2009 02:51 PM

You make a perfect educated point.

But it seems you drive a hell of a lot, and most of it likely highway miles (right? 200 miles of city... I don't think so), so obviously, there is lowered stress as to constant stop and go, and short rides.

Performance wise, I don't know pure numbers, but because oil companies are so secretive about their formulation makes it difficult to determine what group oils are a part of. I don't know if AMSOIL is group 4 or 5 (my guess is a little of both with a PAO base stock versus pure polyol ester stock).

LiquidZ 07-11-2009 06:52 PM

Quote:

Originally Posted by homeslice (Post 111949)
I don't think anyone who works for Amsoil logs into any message boards.

The thing that gets me is that people here and every place end blindly buy oil with no ASTM testing behind it. That's like buying a car without knowing the horsepower and torque it has and buying the car just because you saw many ads for it on TV. That's the wrong reason to buy something.

All of those people using Royal Purple or Red Line would be just as happy or happier with Amsoil. And when you save money with the extended drains with Amsoil (something that Red Line and Royal Purple doesn't do), then you can laugh all the way to the bank.

I use to have a job I was commuting nearly 200 miles per day and I decided to try out the Amsoil 0W30 since this oil is rated to last up to a whopping 35,000 miles (not a typo here for 3,500... that was THIRTY-FIVE THOUSAND miles.)

I decided to give this oil a run for the money and see if it truly performed. I drove an entire 35,000 miles on this oil since I did not want to keep spending money on oil changes every 3 weeks or so. Sure enough, this oil totally lived up to my expectations. My gas mileage increased by a few MPG's and I had ZERO oil consumption in that entire 35,000 miles.

I did however have to change the oil filter mid-way since Amsoil does not have any oil filters that has a full 35,000 miles.

Going that far on the oil was equivalent to 11 oil changes. If Amsoil was good enough to last me a whopping 35,000 miles, I would think going 7,500 to 10,000 for most of the people on here should be perfect.

There's no benefit at all of using Royal Purple over Amsoil. Royal Purple is not going to outperform Amsoil in any way. Plus the fact that Royal Purple costs more money in both the bottle itself and having to change it early.

Fast & Fours magazine did a comparison for many popular oils a long time ago and compared Amsoil to Royal Purple. Amsoil beat Royal Purple.

Synthetic engine / motor oil comparison - Amsoil beats Royal Purple, Mobil 1, Castrol, Hi-Tec, BP, Torco and Shell on the dynometer.

So knowing this, I don't see a reason to use Royal Purple. Where was Royal Purple, Mobil 1 or Red Line back in 1972 when Amsoil was selling synthetic oil? Those companies weren't even wet dreams back then.

I have tried virtually every synthetic oil under the sun over the years. Amsoil has done everything the other oils have done with the ability to go a LOT longer. All the people I know who use Amsoil would never switch to anything else once you get hooked on those 1 year oil changes. Buying Amsoil and changing it every 5,000 miles is foolish. You're simply throwing away your money changing it that early. It doesn't hurt the engine in any way, shape or form going the full 20,000+ miles that it was designed to do... UNLESS you don't have the proper oil filter. If you're using Amsoil and some cheapie Fram or Purolator oil filter, then yeah, you're going to have issues. You'll need to change those cheapie filters often.

My 300 takes an Amsoil EAO38 oil filter. That oil filter is a lot more expensive than the Fram's and Purolators, but it lasts up to 25,000 miles while those cheap filters are only rated for short drains.

I don't know about you guys, but I have a family and a day job. I'm very busy and the last thing I want to be doing is spending time doing oil changes every other month and crap.

My main concern now with oil is will it prevent the "ticking" sound from the VVEL valvetrain without Nissan's "magic" dino juice. I am not doubting Amsoil in any way and I will likely go with it, however, Nissan has brainwashed me into thinking I need their oil to protect my valvetrain.

I know Amsoil is well known for extended drains, but I was wondering, do you have a UOA with a TBN analysis to see how much oil life you had left (or any)?

Additionally, do you happen to know for a fact if Amsoil adds esters to its group IV PAO 5W-30? I have heard two different stories.

FricFrac 08-05-2009 03:05 PM

Quote:

Originally Posted by Robert_Nash (Post 57812)
Just FYI Folks,

I just had my first oil change at my Nissan dealer and according to my service manager, there is now a specific service bulletin from Nissan regarding making the ester oil highly recommended although not required for the 3.7 engine.

Also interesting is that this oil is apparently a Penzoil Platinum product and qualifies for their current $50 rebate after the proscribed number of oil changes.

Now; I haven't confirmed any of the above with Nissan Corporate but that is what the dealer told me.

Have you gotten confirmation yet about this being a Pennzoil Platinum product yet?

fuct 08-05-2009 03:31 PM

""I did however have to change the oil filter mid-way since Amsoil does not have any oil filters that has a full 35,000 miles.""



homeslice:: how did you change your filter without changing the oil? wouldnt oil run all out the filter hole once its off?

kdoske 08-05-2009 04:38 PM

I want to change my own oil but my nissan service tech told he wouldn't recommend it. Not becuase of the quality of oil I may use instead but because of warranty issues.

He claims that not having a record with Nissan of oil changes could put you at risk of your warranty if something were to go wrong with your engine. Is there any truth to this or is this just a scare tactic to make you use their service department???

I mean really? this warranty stuff is getting crazy no?

VCuomo 08-05-2009 04:58 PM

Quote:

Originally Posted by kdoske (Post 139261)
I want to change my own oil but my nissan service tech told he wouldn't recommend it. Not becuase of the quality of oil I may use instead but because of warranty issues.

He claims that not having a record with Nissan of oil changes could put you at risk of your warranty if something were to go wrong with your engine. Is there any truth to this or is this just a scare tactic to make you use their service department???

I mean really? this warranty stuff is getting crazy no?

Scare tactic. Your Nissan service tech is full of shiite. You do NOT need "a record with Nissan of oil changes" in order for the warranty to remain valid - the courts ruled on that BS a long time ago.

But FOR SURE keep a written log of your oil changes - include the date and miles on the odometer.

spearfish25 08-05-2009 04:58 PM

Changing your own oil does not void your warranty.

davidyan 08-07-2009 11:47 PM

Quote:

Originally Posted by spearfish25 (Post 139270)
Changing your own oil does not void your warranty.

It only voids your warranty if you mess up the oil change and as a result caused some damage to your engine.

Valentino 08-31-2009 07:28 AM

So is Nissan Ester Oil considered a Non Synthetic , semi Synthetic, or a Full Synthetic oil?

Sorry if the answer is concluded in some of the posts or in an attached link, but i don't understand most of it, and i got confused and lost.

davidyan 08-31-2009 09:57 PM

Quote:

Originally Posted by Valentino (Post 179792)
So is Nissan Ester Oil considered a Non Synthetic , semi Synthetic, or a Full Synthetic oil?

Sorry if the answer is concluded in some of the posts or in an attached link, but i don't understand most of it, and i got confused and lost.

The nissan ester is not Synthetic. Its probably the only non-synthetics with Ester in it. Many have concluded that they are better off with a good synthetic like Redline which also has Esters. Also, there has been no valve ticking noise with RL or other high quality synthetics.

Valentino 08-31-2009 11:03 PM

^ Thanks.

VCuomo 08-31-2009 11:08 PM

Quote:

Originally Posted by davidyan (Post 181121)
The nissan ester is not Synthetic. Its probably the only non-synthetics with Ester in it. Many have concluded that they are better off with a good synthetic like Redline which also has Esters. Also, there has been no valve ticking noise with RL or other high quality synthetics.

IIRC, the Nissan oil is a synthetic blend (i.e., part synthetic and part dino) - like Castrol Syntec Blend.

FricFrac 09-01-2009 12:26 AM

Quote:

Originally Posted by davidyan (Post 181121)
The nissan ester is not Synthetic. Its probably the only non-synthetics with Ester in it. Many have concluded that they are better off with a good synthetic like Redline which also has Esters. Also, there has been no valve ticking noise with RL or other high quality synthetics.

I don't mean to be a doubting Thomas but do we have any links that backs this up? So far I've heard its based on a synthetic blend and others say its a dino oil with Esters added. No links to the manufactures specs or any lab tests done on the oil so either way its hearsay until someone gives us some evidence either way.

I've read about people who have had ticking on the G37 that was resolved with the TSB regarding the ticking sound that uses both a flash and the Ester oil as the fix. Do we have any links to people who have fixed their ticking with Redline, etc?

Blown32 09-01-2009 10:48 AM

I see everyone is still beating this oil subject to death that is absolutely not a problem at all!
Can only make some of the people happy some of the time but can't make all of the people happy all of the time.Quit worrying!Just put a good quality of oil of YOUR choice in and enjoy the car.
Oil is like opinions and you know how that goes.We all have one!

VCuomo 09-01-2009 11:20 AM

Quote:

Originally Posted by Blown32 (Post 181568)
I see everyone is still beating this oil subject to death that is absolutely not a problem at all!
Can only make some of the people happy some of the time but can't make all of the people happy all of the time.Quit worrying!Just put a good quality of oil of YOUR choice in and enjoy the car.
Oil is like opinions and you know how that goes.We all have one!

Ummmm...this "continuation" was just someone asking if anyone knows what kind of oil Nissan uses at the factory... not a big deal.

Mike 09-01-2009 12:13 PM

Quote:

Originally Posted by kdoske (Post 139261)
I want to change my own oil but my nissan service tech told he wouldn't recommend it. Not becuase of the quality of oil I may use instead but because of warranty issues.

He claims that not having a record with Nissan of oil changes could put you at risk of your warranty if something were to go wrong with your engine. Is there any truth to this or is this just a scare tactic to make you use their service department???

I mean really? this warranty stuff is getting crazy no?

I had the engine replaced in my 350z under warranty for fuel consumption. My receipt for 10 genuine nissan oil filters was good enough to show that I did regular oil changes.

wstar 09-01-2009 12:14 PM

Quote:

Originally Posted by FricFrac (Post 181305)
I don't mean to be a doubting Thomas but do we have any links that backs this up? So far I've heard its based on a synthetic blend and others say its a dino oil with Esters added. No links to the manufactures specs or any lab tests done on the oil so either way its hearsay until someone gives us some evidence either way.

The issue of what is or isn't "synthetic oil" is complicated if you dig too deep :) The manufacturers seem to be happy with the very lax definitions of the term, because it gives them a lot of room to do marketing. Given the different things "synthetic" can mean, and the fact that Nissan Ester is almost certainly a mix of both synthetic and non-synthetic ingredients, there's no 100% clear, hard answer to your question.

Quote:

I've read about people who have had ticking on the G37 that was resolved with the TSB regarding the ticking sound that uses both a flash and the Ester oil as the fix. Do we have any links to people who have fixed their ticking with Redline, etc?
The original problem in the G37 was initially fixed by switching to ester, and then later a TSB came out that involved reflashing the ECU (presumably to change something about the VVEL's parameters), which supposedly cleared up the ticking regardless of the oil type used. We have newer ECUs that undoubtedly incorporate that software fix, and our service manuals recommend but do not require Nissan Ester oil (and most Nissan dealerships seem to have never heard of it unless the customer makes them research it).

Blown32 09-01-2009 12:15 PM

Quote:

Originally Posted by VCuomo (Post 181623)
Ummmm...this "continuation" was just someone asking if anyone knows what kind of oil Nissan uses at the factory... not a big deal.

If you read this from the beginning that question was answered many times many posts ago.Sometimes it is good info to read from the begining because there is alot of valuable info.

FricFrac 09-01-2009 02:38 PM

Quote:

Originally Posted by Blown32 (Post 181709)
If you read this from the beginning that question was answered many times many posts ago.Sometimes it is good info to read from the begining because there is alot of valuable info.

I HAVE read the whole thread. I also am using a good synthetic oil so its not like I need to use the Nissan Ester oil - I've already made my decision based on what I know on the subject.

My questions are a) because I'm interested in the answer. I like knowing how things work, etc. and b) because I dislike when there is information floating around that isn't backed by any evidence then someone comes along and reads the thread and thinks its a fact. I don't have a problem with "Nissan isn't going to tell us because they want to protect the formuation of their super oil", etc. But to says it IS something without any real evidence I'm gonna call it out because its not fair to the next guy who reads it and thinks its a fact. Unfortuantely people don't always think for themselves or verify if what people say are actually true and end up going down a rabbit trail which can sometimes cost them in the end.

Blown32 09-01-2009 03:32 PM

Unfortunetly my friend from abroad there will always be rumors and misinformation flying around these forums because some are easily mislead and believe everything they hear.Also as the tale goes from man to man it is told different each and eveytime.So it is hard to satify all completely.
Use your own good judgement from what you know to be fact and come to your own conclusion.
Hows the weather over there?

VCuomo 09-01-2009 04:03 PM

Quote:

Originally Posted by Blown32 (Post 181709)
If you read this from the beginning that question was answered many times many posts ago.Sometimes it is good info to read from the begining because there is alot of valuable info.

I have read this from the beginning. Perhaps you should read what Valentino posted when he asked if anyone knew what type of oil Nissan uses:

Quote:

Originally Posted by Valentino (Post 179792)
Sorry if the answer is concluded in some of the posts or in an attached link, but i don't understand most of it, and i got confused and lost.

So, again, not a big deal...

davidyan 09-26-2009 09:11 PM

Sorry to reopen, but here is a good article from bobistheoilguy on Esters and motor oils. The article specifically addresses when its in synthetics (for ex. RL) but I don't think it makes much of a difference when applied to dino like the Nissan oil. Here it is:

ESTERS IN SYNTHETIC LUBRICANTS

By T. G. Schaefer


In the simplest terms, esters can be defined as the reaction products of acids and alcohols. Thousands of different kinds of esters are commercially produced for a broad range of applications. Within the realm of synthetic lubrication, a relatively small but still substantial family of esters have been found to be very useful in severe environment applications. This paper shall provide a general overview of the more common esters used in synthetic lubricants and discuss their important benefits and utilities.

Esters have been used successfully in lubrication for more than 60 years and are the preferred stock in many severe applications where their benefits solve problems or bring value. For example, esters have been used exclusively in jet engine lubricants worldwide for over 50 years due to their unique combination of low temperature flowability with clean high temperature operation. Esters are also the preferred stock in the new synthetic refrigeration lubricants used with CFC replacement refrigerants. Here the combination of branching and polarity make the esters miscible with the HFC refrigerants and improves both low and high temperature performance characteristics. In automotive applications, the first qualified synthetic crankcase motor oils were based entirely on ester formulations and these products were quite successful when properly formulated. Esters have given way to PAOs in this application due to PAOs lower cost and their formulating similarities to mineral oil. Nevertheless, esters are often used in combination with PAOs in full synthetic motor oils in order to balance the effect on seals, solubilize additives, reduce volatility, and improve energy efficiency through higher lubricity. The percentage of ester used can vary anywhere from 5 to 25% depending upon the desired properties and the type of ester employed.

The new frontier for esters is the industrial marketplace where the number of products, applications, and operating conditions is enormous. In many cases, the very same equipment which operates satisfactorily on mineral oil in one plant could benefit greatly from the use of an ester lubricant in another plant where the equipment is operated under more severe conditions. This is a marketplace where old problems or new challenges can arise at any time or any location. The high performance properties and custom design versatility of esters is ideally suited to solve these problems. Ester lubricants have already captured certain niches in the industrial market such as reciprocating air compressors and high temperature industrial oven chain lubricants. When one focuses on temperature extremes and their telltale signs such as smoking and deposits, the potential applications for the problem solving ester lubricants are virtually endless.

Ester Chemistry

In many ways esters are very similar to the more commonly known and used synthetic hydrocarbons or PAOs. Like PAOs, esters are synthesized from relatively pure and simple starting materials to produce predetermined molecular structures designed specifically for high performance lubrication. Both types of synthetic basestocks are primarily branched hydrocarbons which are thermally stable, have high viscosity indices, and lack the undesirable and unstable impurities found in conventional petroleum based oils. The primary structural difference between esters and PAOs is the presence of oxygen in the hydrocarbon molecules in the form of multiple ester linkages (COOR) which impart polarity to the molecules. This polarity affects the way esters behave as lubricants in the following ways:

1) Volatility: The polarity of the ester molecules causes them to be attracted to one another and this intermolecular attraction requires more energy (heat) for the esters to transfer from a liquid to a gaseous state. Therefore, at a given molecular weight or viscosity, the esters will exhibit a lower vapor pressure which translates into a higher flash point and a lower rate of evaporation for the lubricant. Generally speaking, the more ester linkages in a specific ester, the higher its flash point and the lower its volatility.

2) Lubricity: Polarity also causes the ester molecules to be attracted to positively charged metal surfaces. As a result, the molecules tend to line up on the metal surface creating a film which requires additional energy (load) to wipe them off. The result is a stronger film which translates into higher lubricity and lower energy consumption in lubricant applications.

3) Detergency/Dispersency: The polar nature of esters also makes them good solvents and dispersants. This allows the esters to solubilize or disperse oil degradation by-products which might otherwise be deposited as varnish or sludge, and translates into cleaner operation and improved additive solubility in the final lubricant.

4) Biodegradability: While stable against oxidative and thermal breakdown, the ester linkage provides a vulnerable site for microbes to begin their work of biodegrading the ester molecule. This translates into very high biodegradability rates for ester lubricants and allows more environmentally friendly products to be formulated.

Another important difference between esters and PAOs is the incredible versatility in the design of ester molecules due to the high number of commercially available acids and alcohols from which to choose. For example, if one is seeking a 6 cSt synthetic basestock, the choices available with PAOs are a straight cut 6 cSt or a “dumbbell” blend of a lighter and heavier PAO. In either case, the properties of the resulting basestock are essentially the same. With esters, literally dozens of 6 cSt products can be designed each with a different chemical structure selected for the specific desired property. This allows the “ester engineer” to custom design the structure of the ester molecules to an optimized set of properties determined by the end customer or application. The performance properties that can be varied in ester design include viscosity, viscosity index, volatility, high temperature coking tendencies, biodegradability, lubricity, hydrolytic stability, additive solubility, and seal compatibility.

As with any product, there are also downsides to esters. The most common concern when formulating with ester basestocks is compatibility with the elastomer material used in the seals. All esters will tend to swell and soften most elastomer seals however, the degree to which they do so can be controlled through proper selection. When seal swell is desirable, such as in balancing the seal shrinkage and hardening characteristics of PAOs, more polar esters should be used such as those with lower molecular weight and/or higher number of ester linkages. When used as the exclusive basestock, the ester should be designed for compatibility with seals or the seals should be changed to those types which are more compatible with esters.

Another potential disadvantage with esters is their ability to react with water or hydrolyze under certain conditions. Generally this hydrolysis reaction requires the presence of water and heat with a relatively strong acid or base to catalyze the reaction. Since esters are usually used in very high temperature applications, high amounts of water are usually not present and hydrolysis is rarely a problem in actual use. Where the application environment may lead to hydrolysis, the ester structure can be altered to greatly improve its hydrolytic stability and additives can be selected to minimize any effects.

The following is a discussion of the structures and features of the more common ester families used in synthetic lubrication.

Diesters

Diesters were the original ester structures introduced to synthetic lubricants during the second World War. These products are made by reacting monohydric alcohols with dibasic acids creating a molecule which may be linear, branched, or aromatic and with two ester groups. Diesters which are often abbreviated DBE (dibasic acid esters) are named after the type of dibasic acid used and are often abbreviated with letters. For example, a diester made by reacting isodecyl alcohol with adipic acid would be known as an “adipate” type diester and would be abbreviated “DIDA” (Diisodecyl Adipate).

Listed below are the more common families of diesters used in synthetic lubricants, and the alcohols most commonly employed.

Adipates are the most widely used diesters due to their low relative cost and good balance of properties. They generally range from about 2.3 to 5.3 cSt at 100°C and exhibit pour points below -60°C. The viscosity indices of adipates usually run from about 130 to 150 and their oxidative stability, like most of the diesters, are comparable to PAOs. The primary difference between adipate diesters and PAOs is the presence of two ester linkages and the associated polarity benefits outlined previously. The most common use of adipate diesters is in combination with PAOs in numerous applications such as screw compressor oils, gear and transmission oils, automotive crankcase oils, and hydraulic fluids. Adipates are also used as the sole basestock where biodegradability is desired or high temperature cleanliness is critical such as in textile lubricants and oven chain oils.

Azelates, Sebacates, and Dodecanedioates are similar to adipates except that in each case the carbon chain length (backbone) of the dibasic acid is longer. This “backbone stretching” significantly increases viscosity index and improves the lubricity characteristics of the ester while retaining all the desirable properties of the adipates. The only downside to these types of diesters is price which tends to run about 50 - 100+% higher than adipates at the wholesale level. This group of linear DBEs are mainly used in older military specifications and where the lubricity factor becomes an important parameter.

Phthalates are aromatic diesters and this ring structure greatly reduces the viscosity index (usually well below 100) and eliminates most of the biodegradability benefit. In all other respects, phthalates behave similar to other diesters and are about 20 - 30% lower in cost. Phthalates are used extensively in air compressor lubricants (especially the reciprocating type) where low viscosity index is the norm and low cost clean operation is desirable.

Dimerates are made by combining two oleic acids which creates a large branched dibasic acid from which interesting diesters are made. Dimerates exhibit high viscosity and high viscosity indices while retaining excellent low temperature flow. Compared to adipates, dimerates are higher in price (30 - 40%), have marginal biodegradability, and are not as clean in high temperature operations. Their lubricity is good and they are often used in synthetic gear oils and 2-cycle oils.

The alcohols used to make diesters will also affect the properties of the finished esters and thus are important factors in the design process. For example, three of the common alcohols used to make diesters each contain eight carbons, and when reacted with adipic acid, all create a dioctyl adipate. However, the properties are entirely different. The n-octyl adipate would have the highest viscosity and the highest viscosity index (about 50% higher then the 2-ethylhexyl adipate) but would exhibit a relatively high freeze point making their use in low temperature applications virtually impossible. By branching the octyl alcohol, the other two DOAs exhibit no freeze point tendencies and have pour points well below -60°C. The isooctyl adipate offers the best balance of properties combining a high viscosity index with a wide temperature range. The 2-ethylhexyl adipate has a VI about 45 units lower and a somewhat higher volatility. These examples demonstrate the importance of combining the right alcohols with the right acids when designing diester structures and allows the ester engineer a great deal of flexibility in his work. In addition, the alcohols may be reacted alone or blended with other alcohols to form coesters with their own unique properties.

Polyol Esters

The term “polyol esters” is short for neopentyl polyol esters which are made by reacting monobasic acids with polyhedric alcohols having a neopentyl structure. The unique feature of the structure of polyol ester molecules is the fact that there are no hydrogens on the beta-carbon. Since this “beta-hydrogen” is the first site of thermal attack on diesters, eliminating this site substantially elevates the thermal stability of polyol esters and allows them to be used at much higher temperatures. In addition, polyol esters usually have more ester groups than the diesters and this added polarity further reduces volatility and enhances the lubricity characteristics while retaining all the other desirable properties inherent with diesters. This makes polyol esters ideally suited for the higher temperature applications where the performance of diesters and PAOs begin to fade.

Like diesters, many different acids and alcohols are available for manufacturing polyol esters and indeed an even greater number of permutations are possible due to the multiple ester linkages. Unlike diesters, polyol esters (POEs) are named after the alcohol instead of the acid and the acids are often represented by their carbon chain length. For example, a polyol ester made by reacting a mixture of nC8 and nC10 fatty acids with trimethylolpropane alcohol would be referred to as a “TMP” ester and represented as TMP C8C10. The following is a list of the more common types of polyol esters:

Neopentyl Glycols (NPGs) - 2 Hydroxyls
Trimethylolpropanes (TMPs) - 3 Hydroxyls
Pentaerythritols (PEs) - 4 Hydroxyls
DiPentaerythritols (DiPEs) - 6 Hydroxyls

Each of the alcohols shown above have no beta-hydrogens and differ primarily in the number of hydroxyl groups they contain for reaction with the fatty acids. The difference in ester properties as they relate to the alcohols are primarily those related to molecular weight such as viscosity, pour point, flash point, and volatility. The versatility in designing these fluids is primarily related to the selection and mix of the acids esterified onto the alcohols.

The normal or linear acids all contribute similar performance properties with the physicals being influenced by their carbon chain length or molecular weight. For example, lighter acids such as C5 may be desirable for reducing low temperature viscosity on the higher alcohols, or the same purpose can be achieved by esterifying longer acids (C10) onto the shorter alcohols. While the properties of the normal acids are mainly related to the chain length, there are some more subtle differences among them which can allow the formulator to vary such properties as thermal stability and lubricity.

Branched acids add a new dimension since the length, location, and number of branches all impact the performance of the final ester. For example, a branch incorporated near the acid group may help to hinder hydrolysis while multiple branches may be useful for building viscosity, improving low temperature flow, and enhancing thermal stability and cleanliness. The versatility of this family is best understood when one considers that multiple acids are usually co-esterified with the polyol alcohol allowing the ester engineer to control multiple properties in a single ester. Indeed single acids are rarely used in polyol esters because of the enchanced properties that can be obtained through co-esterification.

Polyol esters can extend the high temperature operating range of a lubricant by as much as 50 - 100°C due to their superior stability and low volatility. They are also renowned for their film strength and increased lubricity which is useful in reducing energy consumption in many applications. The only downside of polyol esters compared to diesters is their higher price tag, generally 20 - 70+% higher on a wholesale basis.

The major application for polyol esters is jet engine lubricants where they have been used exclusively for more than 40 years. In this application, the oil is expected to flow at -65°C, pump readily at -40°C, and withstand sump temperature over 200°C with drain intervals measured in years. Only polyol esters have been found to satisfy this demanding application and incorporating even small amounts of diesters or PAOs will cause the lubricant to fail vital specifications.Polyol esters are also the ester of choice for blending with PAOs in passenger car motor oils. This change from lower cost diesters to polyols was driven primarily by the need for reduced fuel consumption and lower volatility in modern specifications. They are sometimes used in 2-cycle oils as well for the same reasons. In industrial markets polyol esters are used extensively in synthetic refrigeration lubricants due to their miscibility with non-chlorine refrigerants. They are also widely used in very high temperature operations such as industrial oven chains, tenter frames, stationary turbine engines, high temperature grease, fire resistant transformer coolants, fire resistant hydraulic fluids, and textile lubricants.

In general, polyol esters represent the highest performance level available for high temperature applications at a reasonable price. Although they cost more than many other types of synthetics, the benefits often combine to make this chemistry the most cost effective in severe environment applications. The primary benefits include extended life, higher temperature operation, reduced maintenance and downtime, lower energy consumption, reduced smoke and disposal, and biodegradability.

Other esters

While diesters and polyol esters represent the most widely used ester families in synthetic lubrication, two other families are worth mentioning. These are monoesters and trimellitates.

Monoesters are made by reacting monohydric alcohols with monobasic fatty acids creating a molecule with a single ester linkage and linear or branched alkyl groups. These products are generally very low in viscosity (usually under 2 cSt at 100°C) and exhibit extremely low pour points and high VIs. The presence of the ester linkage imparts polarity which helps to offset the high volatility expected with such small molecules. Hence, when compared to a hydrocarbon of equal molecular weight, a monoester will have a significantly higher flash point giving it a broader temperature range in use. Monoesters are used primarily for extremely cold applications such as in Arctic hydraulic oils and deep sea drilling. They can also be used in formulating automotive aftermarket additives to improve cold starting.

Trimellitates are aromatic triesters which are similar to the phthalates described under diesters but with a third ester linkage. By taking on three alcohols, the trimellitates are significantly more viscous then the linear adipates or phthalates. Viscosities range from about 9 to 20 cSt at 100°C. Like phthalates, trimellitates have a low viscosity index and poor biodegradability with a price range between adipates and polyols. Trimellitates are generally used where high viscosity is needed as in gear lubricants, chain lubricants, and grease.

Summary

Esters are a broad and diverse family of synthetic lubricant basestocks which can be custom designed to meet specific physical and performance properties. The inherent polarity of esters improves their performance in lubrication by reducing volatility, increasing lubricity, providing cleaner operation, and making the products biodegradable. A wide range of available raw materials allow an ester designer the ability to optimize a product over a wide range of variables in order to maximize the performance and value to the client. They may be used alone in very high temperature applications for optimum performance or blended with PAOs or other synthetic basestocks where their complementary properties improve the balance of the finished lubricant. Esters have been used in synthetic lubricants for more than 60 years and continue to grow as the drive for efficiency make operating environments more severe. Because of the complexity involved in the designing, selecting, and blending of an ester basestock, the choice of the optimum ester should be left to a qualified ester engineer who can better balance the desired properties.

Pointman 09-26-2009 10:54 PM

Just tell me what to run already!

VCuomo 09-27-2009 04:38 PM

Quote:

Originally Posted by Pointman (Post 214625)
Just tell me what to run already!

Look at the bazillions of cars on the road that are in fine shape - many of those cars have had well over 100K miles on their engines WITHOUT EVER even having a synthetic oil fill! Many years ago I owned a '65 Rambler American sedan that never had synthetic in it (back then there was no synthetic available) - when I junked it it had almost 90K miles on the engine and, although the rest of the car was crap, the engine still ran fine. And then there was my 1983 Subaru wagon that had almost 200K miles on its engine (no rebuild or major work done on the drivetrain) before it was junked. I currently own a '98 Dodge Durango with almost 90K miles on its engine - it's never had anything in it except for 5W30 non-synthetic oil (mostly Pennzoil) and it still runs strong.

I'm old school - just make sure you put in the correct W oil for your driving conditions (for most, that would be 5W30), make sure it has API certification, and change it regularly at 3K to 5K mile intervals and you will be fine no matter what you brand or type (non-synthetic, synthetic, or synthetic blend) you choose. That's what the aforementioned vehicles that I owned all have in common.

Yeah, I know, heresy...

FricFrac 09-28-2009 12:13 AM

... 'cept for with a synthetic oil you want the first number as low as possible - its really only the second one that matters and even at that the flow characteristics when the vechicle is up to temp are very close to each other (flow is one of the most important aspects of your oil for lubrication). Synthetic also holds up better to heat and thermal cycling, esp with car's like ours that run hot.

I wonder about the filters on our cars. I could put four or five of the 370Z filters in my 240Z filter.... I think that was a big aid in helping engines last....

homeslice 09-29-2009 06:48 AM

It never ceases to amaze me that conventional oils are even legal. There's no benefit at all to using them except during break-in. After that, a person should NEVER use them again. Ever person I've known to put in Amsoil has seen some kind of MPG improvement, which negates the cost of their oil.

I have tried just about every synthetic oil on the shelf. Amsoil has given me the most gains and has cost me the least amount of money to use, plus the stuff has all kinds of ASTM testing proving that their oil is better than Mobil 1, Red Line, Royal Purple, Lucas and everything else popular that other people seem to want to bother with.

After I have figured out the gains in MPG, Amsoil has been free ever since I switched over to it. The gas I save far exceeds the cost of the oil which makes it worth it.

If another oil was better, I'd use it. So far nothing I've seen or tried is proven to be any better. I've known many friends or co-workers over the years to have blown engines while using Royal Purple, Red Line and Mobil 1. I have never seen one single person blow an engine while using Amsoil.

If I had the time, I'd become a dealer for Amsoil, but I don't have the experience of making web sites, etc. to do so.

FricFrac 09-30-2009 12:22 AM

Quote:

Originally Posted by homeslice (Post 216931)
It never ceases to amaze me that conventional oils are even legal. There's no benefit at all to using them except during break-in. After that, a person should NEVER use them again. Ever person I've known to put in Amsoil has seen some kind of MPG improvement, which negates the cost of their oil.

I have tried just about every synthetic oil on the shelf. Amsoil has given me the most gains and has cost me the least amount of money to use, plus the stuff has all kinds of ASTM testing proving that their oil is better than Mobil 1, Red Line, Royal Purple, Lucas and everything else popular that other people seem to want to bother with.

After I have figured out the gains in MPG, Amsoil has been free ever since I switched over to it. The gas I save far exceeds the cost of the oil which makes it worth it.

If another oil was better, I'd use it. So far nothing I've seen or tried is proven to be any better. I've known many friends or co-workers over the years to have blown engines while using Royal Purple, Red Line and Mobil 1. I have never seen one single person blow an engine while using Amsoil.

If I had the time, I'd become a dealer for Amsoil, but I don't have the experience of making web sites, etc. to do so.

LOL - this is pretty much the reason I haven't used Amsoil. The "followers" remind me of Amway salesmen. Based on your logic I can put Amsoil in my engine and run 30 lbs of boost on stock internals because you've never seen an engine blow up with Amsoil. Anecdotal stories are not much to go on. Most people have figured out change your oil regularly, keep it topped up and use a synthetic. Other than that you are arguing infinte details that just don't matter. I have no idea how people can say their mileage increased/decreased with any certainty unless the conditions are strictly controlled which is not possible in normal driving conditions. (Elevation, air density, moisture, presure, throttle input, road conditions, etc, etc, etc - there are too many variables and the results are not repeatable which means they are unreliable).

homeslice 10-01-2009 02:18 AM

Quote:

Originally Posted by FricFrac (Post 217952)
LOL - this is pretty much the reason I haven't used Amsoil. The "followers" remind me of Amway salesmen. Based on your logic I can put Amsoil in my engine and run 30 lbs of boost on stock internals because you've never seen an engine blow up with Amsoil. Anecdotal stories are not much to go on. Most people have figured out change your oil regularly, keep it topped up and use a synthetic. Other than that you are arguing infinte details that just don't matter. I have no idea how people can say their mileage increased/decreased with any certainty unless the conditions are strictly controlled which is not possible in normal driving conditions. (Elevation, air density, moisture, presure, throttle input, road conditions, etc, etc, etc - there are too many variables and the results are not repeatable which means they are unreliable).

Okay, then go use a worse performing oil in your car. What do I care?

Why must you come on here and insult me just because I have awesome luck with a product. Just because people have good luck with something, why does that have to have anything to do with Amway? Nobody is selling you anything. Go on and keep using your unproven oils. I would rather use Amsoil at 30 lbs of boost than s-hit oil like Mobile 1 or Royal Purple.

VCuomo 10-01-2009 01:31 PM

BTW, Amway has good products... (and I'm not affiliated with them in any way)

Blown32 10-01-2009 02:09 PM

Quote:

Originally Posted by homeslice (Post 218892)
Okay, then go use a worse performing oil in your car. What do I care?

Why must you come on here and insult me just because I have awesome luck with a product. Just because people have good luck with something, why does that have to have anything to do with Amway? Nobody is selling you anything. Go on and keep using your unproven oils. I would rather use Amsoil at 30 lbs of boost than s-hit oil like Mobile 1 or Royal Purple.

Sh!T like Mobil 1?Where did you get that info?Talk like that you are insulting yourself!

FricFrac 10-01-2009 02:54 PM

Quote:

Originally Posted by homeslice (Post 218892)
Okay, then go use a worse performing oil in your car. What do I care?

Why must you come on here and insult me just because I have awesome luck with a product. Just because people have good luck with something, why does that have to have anything to do with Amway? Nobody is selling you anything. Go on and keep using your unproven oils. I would rather use Amsoil at 30 lbs of boost than s-hit oil like Mobile 1 or Royal Purple.

Right on - please post videos of your car running 30lbs of boost with Amsoil - should be entertaining and an excellent promotional video. Who knows maybe you can get sponsored by Amsoil :rolleyes:

I'm not trying to insult you - I'm just calling you out on bold statements with no facts. You insult yourself when you make statements like Mobill 1 and Royal Purple being unproven oils or engines not blowing up because of the motor oil used. Oil is for lubrication and preventing parts wear - blowing engines up is from overstressing parts - two very different things.

tvfreakazoid 10-01-2009 02:59 PM

Not to go off subject but here's my 2 cents about amway.

They are expensive. I know a few people under amway. It's funny i've been to there big conference they had here in downtown sacramento about 1yr ago. There were a lot of eastern asians (india) people there. The person I went with he is from india. Anyways there were praising the (creator of amway or i guess the CEO) like he was a god. It was kind of surreal if you ask me. Before amway they had a different name before, but they changed it because of lawsuits and what not.
My friend tried recruiting me but in the end I know it wouldn't work. I mean it's possible, but you would literally have to put almost all your time into it and that may not even work especially in this economy.
If you also noticed a lot of people that i spoke with and works for amway they say they make comfortable living.

Quote:

Originally Posted by VCuomo (Post 219134)
BTW, Amway has good products... (and I'm not affiliated with them in any way)


Lug 10-01-2009 03:01 PM

.....prepares self for Amsoil-sponsored link again














:D

semtex 10-01-2009 03:04 PM

Quote:

Originally Posted by Lug (Post 219186)
.....prepares self for Amsoil-sponsored link again













:D

Click here for Amsoil at wholesale prices! Amsoil Wholesale Discount (Seriously, click on the link. It's a joke.) :stirthepot:

FricFrac 10-01-2009 03:15 PM

Lol - I love how we take a serious thread about something that really isn't serious and make it not serious - seriously. ;)

lovethe370z 11-12-2009 08:08 PM

^^ Seriously.

Anyway, I found this and thought I'd share:
Mobil 1 Q&A: Ester Oil and Nissan Engines

Question:
Ester Oil and Nissan Engines
I've just purchased a Nissan 2009 370Z, which has a 3.7 liter engine that produces 332 HP @ 7500 RPM's, and has a compression ratio of 11 to 1. I've been advised by the Service Manager at Cronic Nissan to run Ester Oil in the engine rather than a good grade of oil, like a 5W-30W. He said that Nissan recommends it. Well, I've researched everything I can find regarding the use of Ester Oil in my Nissan 2009 370Z, and I've been unable to find anything that alludes to the use of Ester Oil in the 370Z engine! What's up with the Ester Oil thing? The only use for Ester Oil that I'm familiar with is for air conditioner compressors and other types of compressors!
-- Larry Young, Tyrone, GA

Answer:
We have not been able to get much information on the Nissan Ester Oil but our analysis indicates that it is part or full synthetic oil. Many synthetic oils, including Mobil 1, contain a variety of synthetic fluids, and usually this includes esters. We would recommend Mobil 1 5W-30 or Mobil 1 Extended Performance 5W-30 for these applications.

FricFrac 11-13-2009 01:37 PM

Quote:

Originally Posted by lovethe370z (Post 277452)
^^ Seriously.

Anyway, I found this and thought I'd share:
Mobil 1 Q&A: Ester Oil and Nissan Engines

Question:
Ester Oil and Nissan Engines
I've just purchased a Nissan 2009 370Z, which has a 3.7 liter engine that produces 332 HP @ 7500 RPM's, and has a compression ratio of 11 to 1. I've been advised by the Service Manager at Cronic Nissan to run Ester Oil in the engine rather than a good grade of oil, like a 5W-30W. He said that Nissan recommends it. Well, I've researched everything I can find regarding the use of Ester Oil in my Nissan 2009 370Z, and I've been unable to find anything that alludes to the use of Ester Oil in the 370Z engine! What's up with the Ester Oil thing? The only use for Ester Oil that I'm familiar with is for air conditioner compressors and other types of compressors!
-- Larry Young, Tyrone, GA

Answer:
We have not been able to get much information on the Nissan Ester Oil but our analysis indicates that it is part or full synthetic oil. Many synthetic oils, including Mobil 1, contain a variety of synthetic fluids, and usually this includes esters. We would recommend Mobil 1 5W-30 or Mobil 1 Extended Performance 5W-30 for these applications.

Lol - wouldn't it be funny if they said DON'T use Mobil 1 ;)

Still curious about the tie with Pennzoil Platinum and Nissan Ester Oil....

Blown32 11-13-2009 02:48 PM

This ester oil discussion can go back and forth forever?Personally I believe it is a gimmick by Nissan to sell there oil.No one has any credible data from Nissan and they themselves don't even know what they are talking about?Info varies from dealership to dealership?Of course there are those that are easily sucked into false advertisements and dealer gimmicks.So what ever makes you happy.
As to which oil is best is like asking which soap do you bathe with?I mean this is all a personal preference.As long as you use a reputable name brand oil you will be fine.
In reference to Amsoil better then this or that is a joke!It is no better then Mobil 1 or many other good quality synthetic oils so whoever says Mobil 1 is shyt is in over there head in this discussion and has made a complete fool of themselves.

davidyan 11-14-2009 03:48 AM

Quote:

Originally Posted by Blown32 (Post 278362)
This ester oil discussion can go back and forth forever?Personally I believe it is a gimmick by Nissan to sell there oil.No one has any credible data from Nissan and they themselves don't even know what they are talking about?Info varies from dealership to dealership?Of course there are those that are easily sucked into false advertisements and dealer gimmicks.So what ever makes you happy.
As to which oil is best is like asking which soap do you bathe with?I mean this is all a personal preference.As long as you use a reputable name brand oil you will be fine.
In reference to Amsoil better then this or that is a joke!It is no better then Mobil 1 or many other good quality synthetic oils so whoever says Mobil 1 is shyt is in over there head in this discussion and has made a complete fool of themselves.


Well, I agree with you that the debate will go on forever but the use of Esters in oils does have its benefits including friction reduction and better stability in high temp. How this all started with Nissan is as follows- If you look back at the G37 forums, the oil was initially recommended to reduce the ticking noise level in the valvetrain. The Nissan patent (which I believe was either rejected or still pending eval) on the Ester oil claims to improve fuel economy however. Esters were used to reduce the valvetrain noise as the additive or base depending on % "sticks to metal". It was later identified that the way the engine winds down and revs up contributed to the noise and thus, Nissan/Infiniti reflashed customer's ECU's which got rid of the majority of the problem. Pretty much all 370Z cars will have this done from the factory as the problem was found in early 08 model G37's which share our engine.

While the oil is expensive at anywhere between $9 - 16 a quart and even though there are better oils out there like Redline (which also has esters), I don't buy the argument that Nissan recommended this to simply sell oil as many suggest. Esters in oil are very expensive and if Nissan is sourcing in such low quantity (only the 370Z and new Maxima use it), they aren't banking on making huge profits from it like Redline or Motul is. Castrol and even M1 have moved away from using Esters due to costs and they produce in the mass quanitities. They are using AN instead which is cheaper and mimics the performance of Esters, or at least the oil industry claims this. Nissan is not in the business of marketing oil. Its also not recommended on the GTR which indicates to me they are not just pushing the oil on all their high performance engines. They saw it as a cheap fix to the valvetrain tick issue and probably never rescinded the recommendation after the ECU reflashes took place. That being said, many have used Redline instead as it has Ester and is usually priced similarly to the Nissan Ester oil.

j.arnaldo 11-14-2009 08:17 AM

If you listen well to commercials, every manufacturer says THEIR product is the very best for you--whatever the product may be! Me? Just prior to having my Civilian's card expire (a benefit I had as Federal employee; I could buy at Ft. Buchanan, a military post, up until July of this year), I went ahead and purchased 6-7 cases of 5W30 Mobil 1 and stashed them in the "automotive stuff" closet! I've got enough for a couple or three-years-worth of oil changes for my wife's Pathfinder and my Z! The price per qt? $4.95, with NO excise tax on the engine honey!!!


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