Yes you can layer it. If it is deep as my chip it would take 2 or possibly 3 coats to make it flush eliminating the dimple.
There is no pearl in the Dr. Colorchip paint. All you get is the base coat. It blends well enough to hide small chips. Only person that will notice it is of course you cuz you know its there. Also of course when you wash and polish it you will notice it. However to the casual observer they will not see it unless they are staring at the front bumper for a while to detect any blemishes.
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